Optoelectronic device based on non-polar and semi-polar aluminum indium nitride and aluminum indium gallium nitride alloys

ABSTRACT

A high-power and high-efficiency light emitting device with emission wavelength (λ peak ) ranging from 280 nm to 360 nm is fabricated. The new device structure uses non-polar or semi-polar AlInN and AlInGaN alloys grown on a non-polar or semi-polar bulk GaN substrate.

CROSS REFERENCE TO RELATED APPLICATION

This application claims the benefit under 35 U.S.C. Section 119(e) ofco-pending and commonly-assigned U.S. Provisional Application Ser. No.61/110,449, filed on Oct. 31, 2008, by Roy B. Chung, Zhen Chen, James S.Speck, Steven P. DenBaars, and Shuji Nakamura, entitled “OPTOELECTRONICDEVICE BASED ON NON-POLAR AND SEMI-POLAR ALUMINUM INDIUM NITRIDE ANDALUMINUM INDIUM GALLIUM NITRIDE ALLOYS,” which application isincorporated by reference herein.

BACKGROUND OF THE INVENTION

1. Field of the Invention

This invention relates to nitride-based optoelectronic devices and amethod of fabricating the same.

2. Description of the Related Art

(Note: This application references a number of different publications asindicated throughout the specification by one or more reference numberswithin brackets, e.g., [x]. A list of these different publicationsordered according to these reference numbers can be found below in thesection entitled “References.” Each of these publications isincorporated by reference herein.)

Nitride-based optoelectronics have been extensively studied forfabrication of visible and ultra-violet (UV) light emitting devices.These devices typically have one or more layers of ternary alloys(InGaN, AlGaN, and AlInN), or quaternary alloy (AlInGaN). Continueddevelopments in nitride-based optoelectronic devices have resulted inhigh-power and high-efficiency light emitting diodes (LEDs) and laserdiodes (LDs), especially in the visible spectrum. However, high-powerand high-efficient LEDs and LDs in the deep UV (DUV) region of thespectrum (emitting light with less than roughly 360 nm wavelengths) havenot been achieved due to the difficulties in the growth, and thus poormaterial quality, and the absence of a bulk aluminum nitride (AlN)substrate.

For a nitride-based UV light emitting devices with peak emissionwavelength (λ_(peak)) less than 360 nm, conventional LEDs and LEDscomprise of multiple AlGaN layers and an AlN buffer layer, which arenormally grown on either sapphire or 6H—SiC substrates. Because of thisheteroepitaxial growth, AlN or AlGaN buffer layers bear a dislocationdensity on the order of 10¹⁰ cm⁻², and the dislocations propagatethrough the subsequent layers, resulting in poor material quality.

For indium containing alloys such as InGaN, it is commonly acknowledgedthat the indium clustering provides highly efficient radiativerecombination sites for the carriers, and thus the performance of thedevice is rather insensitive to the dislocations. In contrast,AlGaN-based devices are sensitive to the dislocation density due to theabsence of the indium clustering, and therefore the performance ofAlGaN-based devices is directly affected by the number of thedislocations.

To reduce the dislocation density, various structures and growthtechniques have been studied. For example, a superlattice structure isgrown between a buffer layer and cladding layer, in which thesuperlattice filters out the dislocations propagating from the bufferlayer and is also known to relieve the strain built in from the latticemismatch. This structure improved the device performance of UV LEDs. Thegrowth techniques used in a metal organic chemical vapor deposition(MOCVD), such as a NH₃ flow modulated AlN growth, have successfullyimproved the quality of the AlN buffer layer. Bulk AlN crystals havebeen achieved by hydride vapor phase epitaxy (HVPE) and physical vaportransport (PVT). See References [1-4].

Even with a high quality AlN buffer layer or a bulk AlN substrate, theAlGaN-based device still suffers from the undesirable quantum-confinedStark effect (QCSE) as long as a device is grown along a c-direction inwhich a strong spontaneous polarization exists. Lattice mismatch betweenlayers will induce piezoelectric polarization, which could enhance thedegree of the polarization. The strong built-in electric fields from thepolarizations cause spatial separation between electrons and holes, thatin turn give rise to restricted carrier recombination efficiency,reduced oscillator strength, and red-shifted emission. The built-inelectric field becomes stronger with higher Al composition.

To summarize, conventional AlGaN-based UV light emitting devices sufferfrom high dislocation density due to the absence of a bulk AN substrate,and from QCSE which reduces the radiative recombination efficiency.

To circumvent the problem of dislocations, AlInGaN quaternary alloyshave been introduced in UV light emitting devices, wherein the indiumclustering is expected to improve the device performance. It has beenshown that the photoluminescence (PL) emission intensity ofAlInGaN-based LEDs is approximately one to two orders of magnitudehigher than that of AlGaN-based LEDs. [5] However, the internal quantumefficiency (IQE) of AlInGaN-based LEDs is still around 15%, which issignificantly lower than that of InGaN (50%-70%). The external quantumefficiency is still too low (˜1%) to realize commercially feasible UVemitting devices [5].

SUMMARY OF THE INVENTION

To overcome the limitations in the prior art described above, and toovercome other limitations that will become apparent upon reading andunderstanding the present invention, the present invention describes amethod for fabricating a high-power and high-efficiency light emittingdevice with a peak emission wavelength (λ_(peak)) ranging from 280 nm to360 nm. The present invention also introduces a new device structureusing non-polar or semi-polar AlInN and AlInGaN alloys grown on anon-polar or semi-polar bulk (free standing) GaN substrate.

In one embodiment, the present invention is an optoelectronic device(e.g., LED or LD), comprising one or more light emitting layerscontaining at least Aluminum (Al), Indium (In), and Nitrogen (N), grownor fabricated on a non-polar or semi-polar GaN substrate, wherein thelight emitting layers are non-polar or semi-polar layers.

The optoelectronic device may further comprise one or moreAl_(x)In_(1−x)N or Al_(y)In_(z)Ga_(1−y−z)N layers closelylattice-matched to the non-polar or semi-polar GaN substrate. Theclosely lattice matched layers may be one or more Al_(x)In_(1−x)N orAl_(y)In_(z)Ga_(1−y−z)N layers doped with silicon (Si) for n-typeconductivity (e.g., an n-type cladding layer doped with Si). The devicemay further comprise one or more Al_(x)In_(1−x)N orAl_(y)In_(z)Ga_(1−y−z)N layers doped with Mg for p-type conductivity(e.g., p-type cladding layer doped with magnesium), on the lightemitting active layers. The plurality of Al_(x)In_(1−x)N orAl_(y)In_(z)Ga_(1−y−z)N layers, and the light emitting active layers,may form one or more heterostructures, and the light emitting activelayers may form one or more quantum-well heterostructures. In the above,0≦y≦1, 0≦z≦1, and 0≦y+z≦1.

An indium composition of one or more of the Al_(x)In_(1−x)N orAl_(y)In_(z)Ga_(1−y−z)N layers (typically the active layer) may rangefrom 10% to 30%.

For example, a light emitting device may comprise (a) an Al_(x)In_(1−x)Nor Al_(y)In_(z)Ga_(1−y−z)N based n-type cladding layer on the non-polaror semi-polar GaN substrate; (b) the one or more light emitting layerscomprising an Al_(x)In_(1−x)N or Al_(y)In_(z)Ga_(1−y−z)N based singlequantum well (SQW) or multiple quantum well (MQW) on the n-type claddinglayers; (c) one or more Al_(x)In_(1−x)N or Al_(y)In_(z)Ga_(1−y−z)N basedelectron blocking layers on the quantum well layers; and (d) anAl_(x)In_(1−x)N or Al_(y)In_(z)Ga_(1−y−z)N based p-type cladding layeron the electron blocking layers, (e) wherein the Al_(x)In_(1−x)N orAl_(y)In_(z)Ga_(1−y−z)N layers are non-polar or semi-polar.

In another example, the optoelectronic device may comprise (a) an first(Al,In,Ga)N layer having a first conductivity type; (b) a second(Al,In,Ga)N layer having a second conductivity type; and (c) an(Al,In,Ga)N quantum-well structure comprising an (Al,In,Ga)N quantumwell layer epitaxially on a non-polar or semi-polar plane of a first(Al,In,Ga)N quantum well barrier layer, and a second (Al,In,Ga)N quantumwell barrier layer epitaxially on a non-polar or semi-polar plane of the(Al,In,Ga)N quantum well layer, wherein (1) the quantum well structureis epitaxially on a non-polar or semi-polar plane of the first(Al,In,Ga)N layer such that the (Al,In,Ga)N quantum well structure isbetween the first (Al,In,Ga)N layer and the second (Al,In,Ga)N layer,and (2) the quantum well has a thickness and (Al,In,Ga)N compositionthat emits electroluminescence having a peak wavelength less than 360nanometers (nm). For example, the light emitting device may have a peakemission wavelength ranging from 280 nm to 360 nm.

The (Al,In,Ga)N quantum well structure may be epitaxially on an(Al,In,Ga)N layer, wherein the (Al,In,Ga)N layer has a dislocationdensity of an (Al,In,Ga)N layer that is grown epitaxially on, andclosely lattice matched to, GaN. For example, the dislocation densitymay be less than 10⁶ cm⁻², which is the dislocation density expectedfrom an underlying GaN substrate, and the (Al,In,Ga)N layer does notcomprise a lateral epitaxial overgrowth. For example, “closelylattice-matched” is close enough that there is no relaxation of the filmat the thicknesses grown. No relaxation means no more than thedislocations from the substrate.

The light emitting device may further comprise the (Al,In,Ga)N quantumwell structure epitaxially on a non-polar or semi-polar plane of an(Al,In,Ga)N layer; and a dislocation density of the (Al,In,Ga)N layerthat is sufficiently low, wherein the non-polar or semi-polar plane andthe dislocation density achieve an internal quantum efficiency of thelight emitting device of greater than 15% and an external quantumefficiency of the Light Emitting Device of greater than 1%.

The present invention further discloses a method of fabricating a deepultraviolet light emitting device, comprising fabricating one or moreAl_(x)In_(1−x)N or Al_(y)In_(z)Ga_(1−y−z)N layers with 0≦y≦1, 0≦z≦1, and0≦y+z≦1 on a non-polar or semi-polar GaN substrate, wherein theAl_(x)In_(1−x)N or Al_(y)In_(z)Ga_(1−y−z)N layers are non-polar orsemi-polar. The method typically further comprises epitaxially growingone or more of the Al_(x)In_(1−x)N and Al_(y)In_(z)Ga_(1−y−z)N layers onthe non-polar or semi-polar GaN substrate so that the Al_(x)In_(1−x)Nand Al_(y)In_(z)Ga_(1−y−z)N layers are closely lattice-matched to thenon-polar or semi-polar GaN substrate. The method may further comprisegrowing at least one of the Al_(x)In_(1−x)N and Al_(y)In_(z)Ga_(1−y−z)Nlayers as a light emitting active layer with an indium compositionranging from 10% to 30%.

For example, the method may comprise epitaxially growing one of theAl_(x)In_(1−x)N or Al_(y)In_(z)Ga_(1−y−z)N layers as a firstAl_(x)In_(1−x)N or Al_(y)In_(z)Ga_(1−y−z)N layer having a firstconductivity type, on a non-polar or semi-polar plane of the GaNsubstrate so that the first Al_(x)In_(1−x)N or Al_(y)In_(z)Ga_(1−y−z)Nlayer is closely lattice matched to the GaN substrate; epitaxiallygrowing one of the Al_(x)In_(1−x)N or Al_(y)In_(z)Ga_(1−y−z)N layers asa first Al_(x)In_(1−x)N or Al_(y)In_(z)Ga_(1−y−z)N quantum well barrierlayer, on a non-polar or semi-polar plane of the first Al_(x)In_(1−x)Nor Al_(y)In_(z)Ga_(1−y−z)N layer; epitaxially growing one of theAl_(x)In_(1−x)N or Al_(y)In_(z)Ga_(1−y−z)N layers as an Al_(x)In_(1−x)Nor Al_(y)In_(z)Ga_(1−y−z)N quantum well layer, on a non-polar orsemi-polar plane of the first Al_(x)In_(1−x)N or Al_(y)In_(z)Ga_(1−y−z)Nquantum well barrier layer, and to a thickness and an (Al,In,Ga)Ncomposition that emits electroluminescence having a peak wavelength lessthan 360 nm; epitaxially growing one of the Al_(x)In_(1−x)N orAl_(y)In_(z)Ga_(1−y−z)N layers as a second Al_(x)In_(1−x)N orAl_(y)In_(z)Ga_(1−y−z)N quantum well barrier layer, on a non-polar orsemi-polar plane of the Al_(x)In_(1−x)N or Al_(y)In_(z)Ga_(1−y−z)Nquantum well layer, thereby forming a quantum well structure comprisingthe Al_(x)In_(1−x)N or Al_(y)In_(z)Ga_(1−y−z)N quantum well layerbetween the first Al_(x)In_(1−x)N or Al_(y)In_(z)Ga_(1−y−z)N quantumwell barrier layer and the second Al_(x)In_(1−x)N orAl_(y)In_(z)Ga_(1−y−z)N quantum well barrier layer; and epitaxiallygrowing one of the Al_(x)In_(1−x)N or Al_(y)In_(z)Ga_(1−y−z)N layers, onthe quantum well structure, as a second Al_(x)In_(1−x)N orAl_(y)In_(z)Ga_(1−y−z−)N layer having a second conductivity type.

BRIEF DESCRIPTION OF THE DRAWINGS

Referring now to the drawings in which like reference numbers representcorresponding parts throughout:

FIG. 1 is a flowchart illustrating a method of the present invention.

FIGS. 2( a), 2(b) and 2 c) are cross-sectional schematics illustratingthree possible MQW structures (×4 periods) for non-polar and semi-polarlight emitting devices.

FIG. 3 is a cross-sectional schematic of a final structure of anon-polar or semi-polar UV LED, with emission wavelength ranging from280 nm to 360 nm, and wherein the cladding layer is closelylattice-matched to the GaN substrate.

DETAILED DESCRIPTION OF THE INVENTION

In the following description of the preferred embodiment, reference ismade to the accompanying drawings which form a part hereof, and in whichis shown by way of illustration a specific embodiment in which theinvention may be practiced. It is to be understood that otherembodiments may be utilized and structural changes may be made withoutdeparting from the scope of the present invention.

Overview

The present invention describes a device structure that can be utilizedfor a high-power and high-efficiency LED and LD, in the wavelengthranging from 280 nm to 360 nm, using non-polar or semi-polar AlInN andAlInGaN grown on non-polar or semi-polar GaN. The salient feature of thestructure is that the piezoelectric field is reduced, because AlInN andAlInGaN cladding layers can be closely lattice-matched to GaN. In thenew structure, the spontaneous polarization is also minimized by growingin non-polar or semi-polar crystal orientations. With the relativelywide bandgap and the reduced spontaneous and piezoelectric polarizationeffects, an efficient non-polar or semi-polar AlInN and AlInGaN basedlight emitting device can replace conventional AlGaN-based lightemitting devices.

The present invention can be used to fabricate an optoelectronic deviceemitting light in the wavelength ranging from 280 nm to 360 nm, forexample. Deep UV LEDs produced by the present invention may be usefulfor water- and air-purification, and germicidal and biomedicalinstrumentation systems. LDs in the UV region can be realized, whichwill increase the capacity of optical storage devices. With LEDsemitting in the region of 350 nm and below, a high-power andhigh-efficient white LEDs with the phosphor coating may also beproduced.

Nomenclature

The term “(Al,Ga,In)N” or III-Nitride as used herein is intended to bebroadly construed to include respective nitrides of the single species,Al, Ga, and In, as well as binary, ternary and quaternary compositionsof such Group III metal species. Accordingly, the term (Al, Ga, In)Ncomprehends the compounds AlN, GaN, and InN, as well as the ternarycompounds AlGaN, GaInN, and AlInN, and the quaternary compound AlGaInN,as species included in such nomenclature. When two or more of the (Ga,Al, In) component species are present, all possible compositions,including stoichiometric proportions as well as “off-stoichiometric”proportions (with respect to the relative mole fractions present of eachof the (Ga, Al, In) component species that are present in thecomposition), can be employed within the broad scope of the invention.Accordingly, it will be appreciated that the discussion of the inventionhereinafter in reference to GaN materials is applicable to the formationof various other (Al, Ga, In)N material species. Further, (Al,Ga,In)Nmaterials within the scope of the invention may further include minorquantities of dopants and/or other impurity or inclusional materials.

One approach to eliminating the spontaneous and piezoelectricpolarization effects in Group-III nitride optoelectronic devices is togrow the devices on nonpolar planes of the crystal (e.g., along anon-polar crystal direction, along an a-axis or m-axis of III-Nitride).For example, in GaN crystals, such planes contain equal numbers of Gaand N atoms and are charge-neutral. Furthermore, subsequent nonpolarlayers are equivalent to one another so the bulk crystal will not bepolarized along the growth direction. Two such families ofsymmetry-equivalent nonpolar planes in GaN are the {11-20} family, knowncollectively as a-planes, and the {10-10} family, known collectively asm-planes.

Another approach to reducing polarization effects and effective holemasses in (Ga,Al,In,B)N devices is to grow the devices on semipolarplanes of the crystal. The term “semipolar plane” can be used to referto any plane that cannot be classified as c-plane, a-plane, or m-plane.In crystallographic terms, a semipolar plane would be any plane that hasat least two nonzero h, i, or k Miller indices and a nonzero 1 Millerindex. Some commonly observed examples of semipolar planes include the{11-22}, {10-11}, and {10-13} planes. Other examples of semipolar planesin the wurtzite crystal structure include, but are not limited to,{10-12}, {20-21}, and {10-14}. The nitride crystal's polarization vectorlies neither within such planes or normal to such planes, but ratherlies at some angle inclined relative to the plane's surface normal. Forexample, the {10-11} and {10-13} planes are at 62.98° and 32.06° to thec-plane, respectively.

TECHNICAL DESCRIPTION

The present invention describes a new device structure for UV lightemitting devices. A device, comprising one or more Al_(x)In_(1−x)N,Al_(y)In_(z)Ga_(1−y−z)N, or Al_(y′)In_(z′)Ga_(1−y′−z′)N layers, with0≦y≦1, 0≦z≦1, 0≦y+z≦1, 0≦y′≦1, 0≦z′≦1, and 0≦y′+z′≦1, is grown on anon-polar or semi-polar GaN substrate via MOCVD.

FIG. 1 is a flowchart illustrating a method of the present invention.

Block 100 represents the step of loading a substrate into a reactor. Forthe growth of a light emitting device structure, a bulk non-polar orsemi-polar GaN substrate is loaded into a MOCVD reactor and a reactorpressure is set to a value between 5 torr and 760 torr.

Block 102 represents the step of growing a GaN layer on the substrate.The reactor's heater is turned on and ramped to a set point temperature,under hydrogen and/or nitrogen. Once the temperature reaches the setpoint, 1 μm to 3 μm thick unintentionally doped (UID) GaN or Si-dopedGaN (by flowing DiSilane (Si₂H₄) into the reactor) is grown.

Then, as represented in block 104, the temperature is set to a valuebetween 600° C. and 1000° C. and trimethyl-indium (TMIn),trimethyl-aluminum (TMAl), and ammonia (NH₃) are introduced into thereactor to grow an n-type AlInN or AlInGaN cladding layer on the GaNlayer of block 102. Triethyl-gallium (TEGa) or trimethyl-gallium (TMGa)is used if the desired layer is a quaternary alloy. DiSilane is alsoflowed into the reactor for n-type doping. All the source flows are keptat a constant level until the cladding layer thickness reaches a minimumof 200 nm. An important condition is that the lattice parameter of thecladding layer must be closely matched to the lattice parameter of theGaN substrate to minimize the strain.

Thus, block 104 illustrates an example of epitaxially growing one of theAl_(x)In_(1−x)N or Al_(y)In_(z)Ga_(1−y−z)N layers, e.g., as a firstAl_(x)In_(1−x)N or Al_(y)In_(z)Ga_(1−y−z)N layer having a firstconductivity type, on a non-polar or semi-polar plane of the GaNsubstrate so that the first Al_(x)In_(1−x)N or Al_(y)In_(z)Ga_(1−y−z)Nlayer is closely lattice matched to the non-polar or semi-polar GaNsubstrate.

Block 106 represents growth of the AlInN or AlInGaN active region on then-type cladding grown in block 104. Once the desired n-type AlInN orAlInGaN cladding thickness is achieved, the reactor's temperature setpoint is decreased by 10° C. to 80° C. to incorporate more indium intothe well region. Once the temperature reaches the set point, the AlInGaNbarrier layer is grown. After the desired thickness is achieved, groupIII source flow rates and/or NH₃ flow rates can be either increased ordecreased to obtain the desired composition of the AlInN or AlInGaNactive layer. After growing the active layer (e.g. well layer) to thedesired thickness, normally in between 3 nm and 10 nm, a barrier isgrown on top. This forms a SQW. For example, the AlInN (active welllayer)/AlInGaN (barrier), or AlInGaN (active layer)/AlInGaN (barrier)may be grown and the structure can be repeated to form a MQW. The indiumcomposition may range from 10% to 30% to achieve a desired beak.Possible MQW structures are shown in FIG. 2.

FIGS. 2( a), 2(b), and 2(c) illustrate epitaxially growing one of theAl_(x)In_(1−x)N or Al_(y)In_(z)Ga_(1−y−z)N layers as a firstAl_(x)In_(1−x)N or Al_(y)In_(z)Ga_(1−y−z)N quantum well barrier layer200, on a non-polar or semi-polar plane of the first Al_(x)In_(1−x)N orAl_(y)In_(z)Ga_(1−y−z)N layer grown in block 104; epitaxially growingone of the Al_(x)In_(1−x)N or Al_(y)In_(z)Ga_(1−y−z)N layers as anAl_(y)In_(z)Ga_(1−y−z)N or Al_(x)In_(1−x)N quantum well layer 202, on anon-polar or semi-polar plane 204 of the first

Al_(x)In_(1−x)N or Al_(y)In_(z)Ga_(1−y−z)N quantum well barrier layer200, and to a thickness 206 and an (Al,In,Ga)N composition that emitselectroluminescence having a peak wavelength less than 360 nm; andepitaxially growing one of the Al_(x)In_(1−x)N orAl_(y)In_(z)Ga_(1−y−z)N layers as a second Al_(x)In_(1−x)N orAl_(y)In_(z)Ga_(1−y−-z)N quantum well barrier layer 208, on a non-polaror semi-polar plane 210 of the Al_(x)In_(1−x)N orAl_(y)In_(z)Ga_(1−y−z)N quantum well layer 202, thereby forming aquantum well structure comprising the Al_(x)In_(1−x)N orAl_(y)In_(z)Ga_(1−y−z)N quantum well layer 202 between the firstAl_(y)In_(z)Ga_(1−y−z)N or Al_(x)In_(1−x)N quantum well barrier layer200 and the second Al_(y)In_(z)Ga_(1−y−z)N or Al_(x)In_(1−x)N quantumwell barrier layer 208. In FIGS. 2( a)-(c), the structure is repeated toform a MQW having 4 periods.

In the example of FIG. 2( a), both the first quantum well barrier layer200 and the second quantum well barrier layer 208 areAl_(y)In_(z)Ga_(1−y−z)N, and the quantum well 202 is Al_(x)In_(1−x)N. Inthe example of FIG. 2( b), both the first quantum well barrier layer 200and the second quantum well barrier layer 208 areAl_(y)In_(z)Ga_(1−y−z)N, and the quantum well 202 isAl_(y)In_(z)Ga_(1−y−z)N with a different composition (e.g.,Al_(y′)In_(z)Ga_(1−y′−z′)N) from the barrier layers 200, 208. In theexample of FIG. 2( c), both the first quantum well barrier layer 200 andthe second quantum well barrier layer 208 are Al_(y)Ga_(1−y)N, and thequantum well 202 is Al_(x)In_(1−x)N. For example, at least one of theAl_(x)In_(1−x)N and Al_(y)In_(z)Ga_(1−y−z)N layers 202 may be grown as alight emitting active layer with an indium composition ranging from 10%to 30%.

Block 108 represents growing an electron blocking layer (EBL), on theactive region grown in block 106, wherein the compositions of group IIIspecies in the EBL are adjusted to obtain desired conduction bandoff-set between EBL and the barrier.

Block 110 represents the step of growing a p-type AlInN or AlInGaNcladding layer on the EBL layer grown in block 108. Once a desired EBLthickness is achieved, the reactor's set point temperature is increasedby 10° C. to 80° C. Then, Cp₂Mg is introduced into the reactor toachieve a p-type AlInN or AlInGaN layer. The compositions of the p-typealloys will be the same as that of the n-type alloys. Thus, block 110illustrates an example of epitaxially growing one of the Al_(x)In_(1−x)Nor Al_(y)In_(z)Ga_(1−y−z)N layers, on the EBL of block 108 and quantumwell structure of block 106, as a second Al_(x)In_(1−x)N orAl_(y)In_(z)Ga_(1−y−z)N layer having a second conductivity type.

Then, as represented in Block 112, a p-type GaN contact layer is grownon the p-type cladding layer grown in block 110. For example, a thin andhighly Magnesium (Mg)-doped p-type GaN layer may be grown on top to forma contact layer.

Once the reactor has cooled, the epitaxial wafer comprising a nitridedevice (formed in blocks 100-112) is removed and annealed in a hydrogendeficient ambient for 15 minutes, at a temperature of 700° C., in orderto activate the p-type GaN contact layer grown in block 112 (Mg dopedlayers), as represented in Block 114.

The next step is to fabricate a device. The process for a UV LED isdescribed here as an example. Once the epitaxial wafer is annealed, aphotolithography technique is used to pattern the p-type contact(p-contact) on the wafer (patterning a p-type contact pattern on thep-GaN layer activated in block 114), as represented in Block 116. Then,p-contact metals (20 Å˜100 Å Ni/Au) are deposited by an electron-beamevaporator and annealed under N₂ or N₂/O₂ ambient for 1 minute to 10minutes to form a metal alloy, as represented in Block 118 (depositingand alloying p-contact metals on the patterned p-type GaN layerpatterned in block 116). Then, the p-GaN contact layer is at leastpartially removed by a dry-etching technique, as represented in Block120 (partially removing the p-type GaN contact layer resulting fromblocks 114-118). The step in Block 120 is to remove the light absorbingGaN layer resulting from blocks 114-118 and expose the p-type claddinglayer grown in block 110, as shown in FIG. 3. After this step, a mesa isformed, in the structure resulting from blocks 100-120, by dry-etching,and the etching exposes the n-type cladding layer of block 104, asrepresented in Block 122. Then, n-type contact metals (Ti/Al/Ni/Au) aredeposited and annealed under N₂ or N₂/O₂ ambient for 1 minute to 10minutes to form a metal alloy, as represented in Block 124 (depositingand alloying n-type contact metals on the n-type cladding layer grown inblock 104 and exposed in block 122). Metals for the contact pads arethen deposited using an electron-beam evaporator, as represented byBlock 126 (depositing metals for contact pads on the alloyed p-contactmetals and alloyed n-contact metals of blocks 118 and 124,respectively).

Then, the substrate of block 100 is typically removed, as represented byblock 128 (removing the substrate). Finally, flip chip packaging istypically performed, and a mirror reflector is typically deposited onthe side of the device exposed by the substrate removal of block 128.

FIG. 3 shows an example of a final optoelectronic device 300 (e.g., LEDor LD) structure obtained after implementing the steps discussed above,comprising one or more Al_(x)In_(1−x)N or Al_(y)In_(z)Ga_(1−y−z)N layers302, 304, 306, and 308, with 0≦y≦1, 0≦z≦1, and 0≦y+z≦1, fabricated(e.g., grown) on a non-polar or semi-polar GaN substrate 310 (as shownin e.g., blocks 104, 106, 108 and 110), wherein the Al_(x)In_(1−x)N orAl_(y)In_(z)Ga_(1−y−z)N layers 302, 304, 306, and 308 are non-polar orsemi-polar (i.e., grown in a non-polar or semi-polar direction so that agrowth surface of the layers 302, 304, 306, and 308 is a non-polar plane(e.g., m-plane or a-plane) or semi-polar plane of III-Nitride.

All the layers 302, 304, 306, and 308 contain at least some Indium. TheAl_(x)In_(1−x)N or Al_(y)In_(z)Ga_(1−y−z)N layers 302, 304, 306, and 308may comprise at least Al, In and N, for example.

For example, one or more of the Al_(x)In_(1−x)N orAl_(y)In_(z)Ga_(1−y−z)N layers are closely lattice-matched to thenon-polar or semi-polar GaN substrate 310 (e.g., an Al_(x)In_(1−x)N orAl_(y)In_(z)Ga_(1−y−z)N based n-type cladding layer 302 on the non-polaror semi-polar GaN substrate 310), one or more of the Al_(x)In_(1−x)N orAl_(y)In_(z)Ga_(1−y−z)N layers are doped with Si for n-type conductivity(e.g., the n-type cladding layer doped with silicon 302), one or more ofthe Al_(x)In_(1−x)N or Al_(y)In_(z)Ga_(1−y−z)N layers are doped with Mgfor p-type conductivity (a p-type cladding layer doped with Mg 308), aplurality of the Al_(x)In_(1−x)N or Al_(y)In_(z)Ga_(1−y−z)N layers 302,304, 306, and 308 form one or more heterostructures or one or morequantum-well heterostructures 304 (e.g., an Al_(x)In_(1−x)N orAl_(y)In_(z)Ga_(1−y−z)N based SQW or MQW 304 on the n-type claddinglayers 302). In one example, an indium composition of one or more of theAl_(x)In_(1−x)N or Al_(y)In_(z)Ga_(1−y−z)N 304 layers ranges from 10% to30%.

The device 300 of FIG. 3 further comprises one or more Al_(x)In_(1−x)Nor Al_(y)In_(z)Ga_(1−y−z)N based electron blocking layers (EBLs) 306 onthe quantum well layers 304. The Al_(x)In_(1−x)N orAl_(y)In_(z)Ga_(1−y−z)N based p-type cladding layer 308 is on the one ormore EBLs 306. Also shown is a p⁺⁺ GaN contact layer 312 on the p-typecladding layer 308, a metal contact 314 to the p⁺⁺ GaN contact layer 312and a metal contact 316 to the n-type cladding layer 302.

Layer 302 is typically closely lattice matched to the substrate.“Closely lattice-matched” is close enough that there is no relaxation ofthe film at the thicknesses grown. No relaxation means no moredislocations than the dislocations from the substrate 310.

Thus, FIGS. 2( a), 2(b), 2(c), and 3 illustrate an optoelectronic device300, comprising one or more light emitting layers 202, 304 containing atleast Al, In, and N, grown on a non-polar or semi-polar GaN substrate310, wherein the light emitting layers 202, 304 are non-polar orsemi-polar layers.

FIGS. 2( a), 2(b), 2(c) and 3 also illustrate a first (Al,In,Ga)N layerhaving a first conductivity type 302 (e.g., but not limited to, n-type);a second (Al,In,Ga)N layer having a second conductivity type 308 (e.g.,but not limited to, p-type); an (Al,In,Ga)N quantum-well structure 304comprising an (Al,In,Ga)N quantum well layer 202 epitaxially on anon-polar or semi-polar plane 204 of a first (Al,In,Ga)N quantum wellbarrier layer 200, and a second (Al,In,Ga)N quantum well barrier layer208 epitaxially on a non-polar or semi-polar plane 210 of the(Al,In,Ga)N quantum well layer 202, wherein (1) the quantum wellstructure 304 is epitaxially on a non-polar or semi-polar plane 318 ofan (Al,In,Ga)N layer (e.g., the first (Al,In,Ga)N layer 302) such thatthe (Al,In,Ga)N quantum well structure 304 is between the first(Al,In,Ga)N layer 302 and the second (Al,In,Ga)N layer 308, and thequantum well 202 has a thickness 206 and (Al,In,Ga)N composition thatemits electroluminescence having a peak wavelength less than 360 nm. Forexample, the device 300 may be a light emitting device having a peakemission wavelength ranging from 280 nm to 360 nm.

The (Al,In,Ga)N layer 302 is typically grown on a non-polar orsemi-polar plane 320 of the substrate 310. Even after the substrate 310is subsequently removed (see, e.g., block 128 of FIG. 1), layer 302retains the dislocation density associated with epitaxial growth on GaN.As a result, the (Al,In,Ga)N quantum well structure 304 is epitaxiallyon an (Al,In,Ga)N layer 302, wherein the (Al,In,Ga)N layer 302 has a lowdislocation density of an (Al,In,Ga)N layer that is grown epitaxiallyon, and closely lattice matched to, GaN (e.g., substrate 310), evenafter the substrate 310 is removed. The (Al, In, Ga)N layers 302 mayhave a dislocation density of less than 10⁶ cm⁻², wherein the(Al,In,Ga)N layer 302 (and/or layers between layer 302 and the substrate310, and/or layers 304, 306, and 308) do not comprise a lateralepitaxial overgrowth.

With the sufficiently low dislocation density and the relatively highIndium composition of (Al, In, Ga)N, the active region (light emittingregion) 304 could achieve an IQE of the light emitting device 300 ofgreater than 15%, which was the value obtained by anAl_(x)In_(y)Ga_(1−x−y)N alloy with Indium contents (y) less than 10%.Therefore, it is possible to achieve an external quantum efficiency ofthe light emitting device 300 of greater than 1%.

In general, the dislocations such as edge type dislocations and screwtype dislocations are known to be a trap that provides nonradiativerecombination sites. More dislocations means more nonradiativerecombination and hence lower IQE. Therefore, external quantumefficiency drops (external quantum efficiency=IQE times extractionefficiency).

Details of the fabrication process need to be modified for other UVemitting devices, such as a laser diode.

In order to enhance the utility of the present invention, it isimportant that the device is grown on a bulk GaN substrate, which hasthe minimum possible dislocations. A Bulk GaN substrate is essentially athick GaN that is free standing. One example would be a thick (˜300 μm)GaN grown on a sapphire, which then is lifted-off from the sapphiresubstrate.

However, the GaN substrate is an absorbing layer for the emissionwavelength lower than 360 nm. Therefore, it is necessary to remove theGaN substrate to improve the light extraction, as represented in Block128. The GaN substrate can be removed by lapping, polishing, anddry-etching processes. Then, flip-chip packaging with a mirror reflector(as represented in Block 130) can maximize light extraction from thelight emitting device, such as the LEDs described above.

Possible Modifications

Although the growth specification for the devices described aboveutilized heteroepitaxial growth of non-polar and semi-polar AlInN andAlInGaN layers by MOCVD, the present invention can use any growthtechniques. For example, non-polar and semi-polar AlInN and AlInGaNcould also be grown by molecular beam epitaxy (MBE) with the propergrowth conditions.

Instead of using a dry-etching technique to remove the GaN substrate, avery thin InGaN layer can be deposited prior to the growth of the n-typecladding layer. After a device is grown, the InGaN layer can be etchedaway by photoelectrochemical (PEC) etching using a UV light source.

The growth process described above is only one set of possible growthconditions based on preliminary experiments. Growth conditions such asgas flows, growth pressure, and growth temperature can be furtherexplored to grow non-polar and semi-polar AlInN and AlInGaN layers.Further information on growth of AlInN can be found in [6].

Advantages and Improvements

The existing practice is to grow AlGaN-based UV emitting devices on ac-plane sapphire or SiC substrate in which the surface is either Ga(Al)-face or N-face. The plane normal to the c-direction has spontaneouspolarization due to the large electronegativity difference. Hence, theinterface between multi-layers of different polarization inherentlybuilds up the polarization charge and results in an internal electricfield. This electric field can be significantly large for thin layerssuch as an active layer and changes the energy band structure. Latticemismatch between substrates and subsequent layers (AlN and AlGaN)introduces a piezoelectric polarization, which could further change theband structure.

The present invention describes a device structure that has minimizedboth the spontaneous and piezoelectric polarizations. Spontaneouspolarization is decreased by growing a device in a non-polar orsemi-polar crystal orientation. More importantly, reduction inpiezoelectric polarization is achieved by growing AlInN or AlInGaNcladding layers closely lattice-matched to the GaN substrate. Only thequantum-well layers are slightly under the compressive strain. Thelattice-matching condition also means there are no additionaldislocations arising from the interface between the cladding layer andthe substrate. Therefore, the reduction of both the QCSE effect anddislocation density will result in higher IQE. Improved crystal qualityalso means that high-power and high-efficiency LDs in the UV region canbe realized. Because the non-polar and semi-polar bulk GaN substratesare available with high crystal quality, the new structure described inthe present invention is expected to more efficient than thestate-of-art UV emitting devices that are currently available.

REFERENCES

The following references are incorporated by reference herein:

[1] T. Nishida, H. Saito, and N. Kobayashi, Appl. Phys. Lett. 78, 399(2001).

[2] H. Hirayama, T. Yatabe, N. Noguchi, T. Ohashi, and N. Kamata, Appl.Phys. Lett. 91, 071901 (2007).

[3] D. S. Kamber, Y. Wu, E. Letts, S. P. DenBaars, J. S. Speck, S.Nakamura, and S. A. Newman, Appl. Phys. Lett. 90, 122116 (2007).

[4] G. A. Slack and T. F. McNelly, J. Crys. Growth 34, 263 (1976).

[5] H. Hirayama, J. Appl. Phys. 97, 091101 (2005).

[6] R. B. Chung, Z. Chen, S. Keller, J. S. Speck, S. P. DenBaars, and S.Nakamura, “effect of growth conditions on Indium incorporation duringAlInN growth by MOCVD and characterization”, 36^(th) internationalsymposium on compound semiconductors, August 2009, Santa Barbara,Calif., USA.

CONCLUSION

This concludes the description of the preferred embodiment of thepresent invention. The foregoing description of one or more embodimentsof the invention has been presented for the purposes of illustration anddescription. It is not intended to be exhaustive or to limit theinvention to the precise form disclosed. Many modifications andvariations are possible in light of the above teaching. It is intendedthat the scope of the invention be limited not by this detaileddescription, but rather by the claims appended hereto.

1. An optoelectronic device structure, comprising one or more lightemitting layers containing at least Aluminum (Al), Indium (In), andNitrogen (N), grown on a non-polar or semi-polar Gallium Nitride (GaN)substrate, wherein the light emitting layers are non-polar or semi-polarlayers and emit light having a peak emission at a wavelength of 360 nmor less.
 2. The device structure of claim 1, further comprising one ormore Al_(x)In_(1−x)N or Al_(y)In_(z)Ga_(1−y−z)N layers, with 0≦y≦1,0≦z≦1, and 0≦y+z≦1, closely lattice-matched to the non-polar orsemi-polar GaN substrate.
 3. The device structure of claim 2, whereinthe closely lattice-matched Al_(x)In_(1−x)N or Al_(y)In_(z)Ga_(1−y−z)Nlayers, with 0≦y≦1, 0≦z≦1, and 0≦y+z≦1, are doped with silicon (Si) forn-type conductivity.
 4. The device structure of claim 3, furthercomprising one or more Al_(x)In_(1−x)N or Al_(y)In_(z)Ga_(1−y−z)Nlayers, with 0≦y≦1, 0≦z≦1, and 0≦y+z≦1, doped with Mg for p-typeconductivity, and on the light emitting active layers.
 5. The devicestructure of claim 4, wherein the light emitting active layers, theclosely lattice matched Al_(x)In_(1−x)N or Al_(y)In_(z)Ga_(1−y−z)Nlayers, and the p-type doped Al_(x)In_(1−x)N or Al_(y)In_(z)Ga_(1−y−z)Nlayers form one or more heterostructures.
 6. The device structure ofclaim 4, wherein the p-type doped Al_(x)In_(1−x)N orAl_(y)In_(z)Ga_(1−y−z)N layers, with 0≦y≦1, 0≦z≦1, and 0≦y+z≦1, are ap-type cladding layer, doped with magnesium.
 7. The device structure ofclaim 2, wherein the closely lattice-matched Al_(x)In_(1−x)N orAl_(y)In_(z)Ga_(1−y−z)N layers, with 0≦y≦1, 0≦z≦1, and 0≦y+z≦1, are ann-type cladding layer, doped with silicon Si.
 8. The device structure ofclaim 1, wherein the device is a Light Emitting Diode or Laser Diode. 9.The device structure of claim 1, wherein the light emitting layers havean Indium composition ranging from 10% to 30%.
 10. The device structureof claim 1, wherein the light emitting active layers form one or morequantum-well heterostructures.
 11. The device structure of claim 1,wherein the device is a light emitting device further comprising: (a) anAl_(x)In_(1−x)N or Al_(y)In_(z)Ga_(1−y−z)N based n-type cladding layeron the non-polar or semi-polar GaN substrate; (b) the light emittinglayers comprising an Al_(x)In_(1−x)N or Al_(y)In_(z)Ga_(1−y−z)N basedsingle Quantum well or multiple quantum-well on the n-type claddinglayers; (c) one or more Al_(x)In_(1−x)N or Al_(y)In_(z)Ga_(1−y−z)N basedelectron blocking layers on the Quantum well; and (d) an Al_(x)In_(1−x)Nor Al_(y)In_(z)Ga_(1−y−z)N based p-type cladding layer on the electronblocking layers, (e) wherein the Al_(x)In_(1−x)N orAl_(y)In_(z)Ga_(1−y−z)N layers (a), (b), (c) and (d) are non-polar orsemi-polar and 0≦y≦1, 0≦z≦1, and 0≦y+z≦1.
 12. The device structure ofclaim 1, wherein the device is a light emitting device having the peakemission at the wavelength ranging from 280 nm to 360 nm.
 13. Anoptoelectronic device, comprising: (a) an first (Al,In,Ga)N layer havinga first conductivity type; (b) a second (Al,In,Ga)N layer having asecond conductivity type; and (c) an (Al,In,Ga)N quantum-well structurecomprising an (Al,In,Ga)N quantum well layer epitaxially on a non-polaror semi-polar plane of a first (Al,In,Ga)N quantum well barrier layer,and a second (Al,In,Ga)N quantum well barrier layer epitaxially on anon-polar or semi-polar plane of the (Al,In,Ga)N quantum well layer,wherein: (1) the quantum well structure is epitaxially on a non-polar orsemi-polar plane of the first (Al,In,Ga)N layer such that the(Al,In,Ga)N quantum well structure is between the first (Al,In,Ga)Nlayer and the second (Al,In,Ga)N layer, and (2) the quantum well has athickness and (Al,In,Ga)N composition that emits electroluminescencehaving a peak emission at a wavelength of 360 nm or less.
 14. The deviceof claim 13, further comprising the (Al,In,Ga)N quantum well structureepitaxially on an (Al,In,Ga)N layer, wherein the (Al,In,Ga)N layer has adislocation density of an (Al,In,Ga)N layer that is grown epitaxiallyon, and closely lattice matched to, GaN.
 15. The device of claim 14,wherein the dislocation density is less than 10⁶ cm⁻² and the(Al,In,Ga)N layer does not comprise a lateral epitaxial overgrowth. 16.The device of claim 13, wherein the device is a Light Emitting Device,and further comprising: the (Al,In,Ga)N quantum well structureepitaxially on a non-polar or semi-polar plane of an (Al,In,Ga)N layer;and a dislocation density of the (Al,In,Ga)N layer that is sufficientlylow, wherein the non-polar or semi-polar plane and the dislocationdensity achieve an internal quantum efficiency of the Light EmittingDevice of greater than 15% and an external quantum efficiency of theLight Emitting Device of greater than 1%.
 17. A method of fabricating adeep ultraviolet light emitting device, comprising growing one or moreAl_(x)In_(1−x)N or Al_(y)In_(z)Ga_(1−y−z)N layers with 0≦y≦1, 0≦z≦1, and0≦y+z≦1, on a non-polar or semi-polar Gallium Nitride (GaN) substrate,wherein the Al_(x)In_(1−x)N or Al_(y)In_(z)Ga_(1−y−z)N layers arenon-polar or semi-polar, and at least one of the Al_(x)In_(1−x)N orAl_(y)In_(z)Ga_(1−y−z)N layers are light emitting layers containing atleast Al, In, and N and emit light having a peak emission at awavelength of 360 nm or less.
 18. The method of claim 17, furthercomprising epitaxially growing one or more of the Al_(x)In_(1−x)N andAl_(y)In_(z)Ga_(1−y−z)N layers on the non-polar or semi-polar GaNsubstrate so that the Al_(x)In_(1−x)N and Al_(y)In_(z)Ga_(1−y−z)N layersare closely lattice-matched to the non-polar or semi-polar GaNsubstrate.
 19. The method of claim 17, further comprising growing thelight emitting active layers with an indium composition ranging from 10%to 30%.
 20. The method of claim 17, further comprising: epitaxiallygrowing one of the Al_(x)In_(1−x)N or Al_(y)In_(z)Ga_(1−y−z)N layers asa first Al_(x)In_(1−x)N or Al_(y)In_(z)Ga_(1−y−z)N layer having a firstconductivity type, on a non-polar or semi-polar plane of the GaNsubstrate so that the first Al_(x)In_(1−x)N or Al_(y)In_(z)Ga_(1−y−z)Nlayer is closely lattice matched to the GaN substrate; epitaxiallygrowing one of the Al_(x)In_(1−x)N or Al_(y)In_(z)Ga_(1−y−z)N layers asa first Al_(x)In_(1−x)N Or Al_(y)In_(z)Ga_(1−y−z)N quantum well barrierlayer, on a non-polar or semi-polar plane of the first Al_(x)In_(1−x)Nor Al_(y)In_(z)Ga_(1−y−z)N layer; epitaxially growing one of theAl_(x)In_(1−x)N or Al_(y)In_(z)Ga_(1−y−z)N layers as an Al_(x)In_(1−x)Nor Al_(y)In_(z)Ga_(1−y−z) N quantum well layer, on a non-polar orsemi-polar plane of the first Al_(x)In_(1−x)N or Al_(y)In_(z)Ga_(1−y−z)Nquantum well barrier layer, and to a thickness and an (Al,In,Ga)Ncomposition that emits the electroluminescence having the peak emissionat the wavelength of 360 nm; or less; epitaxially growing one of theAl_(x)In_(1−x)N or Al_(y)In_(z)Ga_(1−y−z)N layers as a secondAl_(x)in_(1−x)N or Al_(y)In_(z)Ga_(1−y−z)N quantum well barrier layer,on a non-polar or semi-polar plane of the Al_(x)In_(1−x)N orAl_(y)In_(z)Ga_(1−y−z)N quantum well layer, thereby forming a quantumwell structure comprising the Al_(x)In_(1−x)N or Al_(y)In_(z)Ga_(1−y−z)Nquantum well layer between the first Al_(x)In_(1−x)N orAl_(y)In_(z)Ga_(1−y−z)N quantum well barrier layer and the secondAl_(x)In_(1−x)N or Al_(y)In_(z)Ga_(1−y−z)N quantum well barrier layer;and epitaxially growing one of the Al_(x)In_(1−x)N orAl_(y)In_(z)Ga_(1−y−z)N layers, on the quantum well structure, as asecond Al_(x)In_(1−x)N or Al_(y)In_(z)Ga_(1−y−z)N layer having a secondconductivity type, wherein the light emitting active layers comprise thequantum well layer.
 21. The device structure of claim 1, wherein thelight emitting layers are removed from the non-polar or semi-polar GaNsubstrate after the light emitting layers are grown.
 22. The devicestructure of claim 1, wherein the device structure emits the light withan internal quantum efficiency greater than 15% and an external quantumefficiency greater than 1%.
 23. The device structure of claim 1, whereinat least some GaN that absorbs the light is removed from the devicestructure.